Studies of Electrochemical Behavior of Composite Electrode ?[Co-(Ortophenontroline) 3] 2+ + Graphite? in Aqueous and THF Media

Z. Modarress Tehrani¹* and J. Mofidi²

¹Department of Chemistry, Al-Zahra University, Vanak Street, Tehran (Iran)

²Islamic Azad University, North Tehran branch, Faculty of Chemistry, Tehran (Iran)

DOI : http://dx.doi.org/10.13005/msri/040110

ABSTRACT:

In this research, we were interest to study the electrochemical behaviour of modified composite electrode" [Co-Ph3]2+, 2ClO4-complex? mixed with ?graphite powder?, at different per cent weights and pressures in aqueous and THF media. According to our results in aqueous solution, 0.1M NaClO4, one irreversible system CoII/CoI (DEp @ 250 mv) and in ?THF + TBAP 0.1M, two irreversible systems CoII/ CoII and CoII/CoIand appear and the later is more irreversible. The main idea is to verify electro-catalytic assis

KEYWORDS: composite electrode; cyclic voltammetry; 110-orthophenantroline- Co (II) complex

Copy the following to cite this article: Tehrani Z. M, Mofidi J. Studies of Electrochemical Behavior of Composite Electrode ?[Co-(Ortophenontroline) 3] 2+ + Graphite? in Aqueous and THF Media. Mat.Sci.Res.India;4(1)

Copy the following to cite this URL: Tehrani Z. M, Mofidi J. Studies of Electrochemical Behavior of Composite Electrode ?[Co-(Ortophenontroline) 3] 2+ + Graphite? in Aqueous and THF Media. Mat.Sci.Res.India;4(1). Available from: http://www.materialsciencejournal.org/?p=1568

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