Coordination Polymers of N,N'-Di(8-Hydroxyquinolinolyl-5) Methyl) N,N' Diethyl-1, 2-Ethane Diamine (Qeed)

S. P. Patel¹*, C. P. Bhasin¹, A. D. Patel¹ and D. S. Raj²

¹Department of Chemistry, Hemachandrachaya North Gujrat University, Patan - 384265 (India)

²Principle, J and J Science College, Nadiad - 387001 (India)

DOI : http://dx.doi.org/10.13005/msri/020104

ABSTRACT:

Cooridnation polymers containing a novel bis(oxine) bidentate ligand namely N,N' -di(8-hydroxyquinolinoly 1-5) -N,N' - diethyl-1,2-ethanediamine (QEED) have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis (bidenate) ligand was synthesized by condensation of 5-chlorometyl-8-hydroxyquinoline hydrochloride with N,N'-diethyl-1,2 ethaanediamne in the presence of a base catalyses. All of these coordination polymers and the parent ligand were characterized by elemental analyses and IR spectra and diffuse reflectance spectral studies. The thermal stability and number-average molecular weight (Mn) of all of the coordination polyerms were determined by Theromgravimetric analyses and non-aquous conductrometric titrations, respectively in addition, all of the coordination polymers have been characterized by their magnetic suspectiblities.

KEYWORDS: Cordination polymers; bis (oxine) bidenate ligand; N;N'-di(8-hydroxyquinolinoyl-5-methyl)-N'N diethy

Copy the following to cite this article: Patel S. P, Bhasin C. P, Patel A. D, Raj D. S. Coordination Polymers of N,N'-Di(8-Hydroxyquinolinolyl-5) Methyl) N,N' Diethyl-1, 2-Ethane Diamine (Qeed). Mat.Sci.Res.India;2(1)

Copy the following to cite this URL: Patel S. P, Bhasin C. P, Patel A. D, Raj D. S. Coordination Polymers of N,N'-Di(8-Hydroxyquinolinolyl-5) Methyl) N,N' Diethyl-1, 2-Ethane Diamine (Qeed). Mat.Sci.Res.India;2(1). Available from: http://www.materialsciencejournal.org/?p=3126

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