Thermodynamic Behaviour of Hypersensitive Transitions Observed in Some Hoiii and Tmiii Doped Systems

R.S. Verma, H.P. Yadav and J.S. Acharya*

Department of Chemistry, Government Dunger College, Bikaner (India)

DOI : http://dx.doi.org/10.13005/msri/032a24

ABSTRACT:

The saturated ligand environment produced by various amino acids in 50% ethanol (v/v) around HoIII and TmIII ions have been studied with respect to hypersensitive transitions. The thermodynamics of hypersensitive transitions have been studied and correlated with spectral parameters. The thermodynamic parameters include work function, thermodynamic efficiency and partition functions of the said transitions. TmIII doped systems exhibit 80% thermodynamic efficiency where as HoIII doped systems show 89% efficiency.

KEYWORDS: Thermodynamic behaviour; hypersensitive transitions; TmIII HoIII doped systems

Copy the following to cite this article: Verma R. S, Yadav H. P, Acharya J. S. Thermodynamic Behaviour of Hypersensitive Transitions Observed in Some Hoiii and Tmiii Doped Systems. Mat.Sci.Res.India;3(2a)

Copy the following to cite this URL: Verma R. S, Yadav H. P, Acharya J. S. Thermodynamic Behaviour of Hypersensitive Transitions Observed in Some Hoiii and Tmiii Doped Systems. Mat.Sci.Res.India;3(2a). Available from: http://www.materialsciencejournal.org/?p=3327

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