Electrical Transport Study of Superionic System Li3po4 : X Li3vo4

Rajesh Kumar Patel, Satyendra Singh and Kanchan Gaur

Department of Physics, K.N. Government P.G. College, Gyanpur, Bhadohi (India).

DOI : http://dx.doi.org/10.13005/msri/040221

ABSTRACT:

Measurement of electrical conductivity (s) and Seebeck coefficient (S) have been performed on the solidified melt of the lithium based superionic system Li3PO4 : x Li3VO4 where x = 0.0, 0.33, 0.50, 0.67, 1.0, 1.5 and 2.0 in the temperature range 500 K to the melting point of the materials. All the studied materials are purely ionic in superionic phase which has been observed below their melting point. At phase transition solids undergo from normal to superionic phase. Ionic and electronic parts of electrical conductivity have also been separated. These solids are mixed conductors in normal phase. Electrical conduction mechanism have also been discussed..

KEYWORDS: Electrical transport; superionic system; electrical conductivity; seebeck coefficient

Copy the following to cite this article: Patel R. K, Singh S, Gaur K. Electrical Transport Study of Superionic System Li3po4 : X Li3vo4. Mat.Sci.Res.India;4(2)

Copy the following to cite this URL: Patel R. K, Singh S, Gaur K. Electrical Transport Study of Superionic System Li3po4 : X Li3vo4. Mat.Sci.Res.India;4(2). Available from: http://www.materialsciencejournal.org/?p=1462

---

This work is licensed under a Creative Commons Attribution 4.0 International License.